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Hastelloy C-22 (UNS N06022): Alloy Composition, Corrosion Resistance and C-276 Comparison
Date:2026-09-10 00:00:00View:23Tags:Nickel Alloy Supplier
NICKEL-BASED CORROSION-RESISTANT ALLOY

Hastelloy C-22 (UNS N06022): Composition, Corrosion Resistance & C-276 Comparison

A technical engineering guide to Hastelloy C-22, covering chemical composition, corrosion resistance, mechanical properties, heat treatment, welding, fabrication, applications and material selection against Hastelloy C-276.

UNS N06022 W.Nr. 2.4602 Ni-Cr-Mo-W Alloy Hastelloy C-22 C-22 vs C-276

1. What Is Hastelloy C-22?

Hastelloy C-22 (UNS N06022) is a nickel-chromium-molybdenum-tungsten alloy developed for severe corrosion environments where conventional stainless steels and many other nickel alloys may not provide sufficient corrosion resistance.

The alloy is particularly valuable when equipment is exposed to changing, contaminated or mixed chemical environments containing both oxidizing and reducing species. Its chemical design combines a relatively high chromium content with substantial molybdenum and tungsten additions.

Engineering principle: C-22 should not be viewed simply as a stronger version of C-276. Its key advantage is the balance between resistance to oxidizing environments, localized corrosion and reducing chemical conditions.

This combination makes Hastelloy C-22 particularly relevant to chemical processing equipment, pollution-control systems, pharmaceutical equipment, marine systems and other applications where corrosion conditions can change during service.

2. Hastelloy C-22 Chemical Composition

The performance of C-22 is strongly related to its Ni-Cr-Mo-W chemistry. Chromium primarily strengthens resistance to oxidizing media, while molybdenum and tungsten contribute significantly to resistance against reducing acids and localized corrosion.

Element Typical / Specified Content (wt.%) Primary Metallurgical Function
Nickel (Ni) Balance Matrix; overall corrosion and structural stability
Chromium (Cr) 20.0–22.5 Passive-film formation and oxidizing-media resistance
Molybdenum (Mo) 12.5–14.5 Reducing-acid and localized corrosion resistance
Tungsten (W) 2.5–3.5 Improves localized and reducing-environment resistance
Iron (Fe) 2.0–6.0 Controlled alloying constituent
Carbon (C) ≤ 0.015 Low level limits carbide precipitation
Silicon (Si) ≤ 0.08 Controlled to minimize detrimental phases
Cobalt (Co) ≤ 2.5 Controlled residual/alloying element
Vanadium (V) ≤ 0.35 Controlled minor alloying element

Why Is Chromium Important in C-22?

Chromium promotes the formation and maintenance of a protective passive film. This is particularly important in oxidizing media, including environments containing nitric acid, ferric ions, cupric ions or wet chlorine.

Why Are Mo and W Added?

Molybdenum and tungsten provide additional resistance to reducing acids and localized corrosion mechanisms such as pitting and crevice corrosion. Their combined effect is an important part of the alloy's performance in complex process environments.

3. Hastelloy C-22 vs C-276: Why Was the Chemistry Redesigned?

Hastelloy C-22 is often compared directly with Hastelloy C-276 because the two alloys share the same fundamental Ni-Cr-Mo-W design philosophy. However, their alloy chemistry reflects different optimization priorities.

For a separate technical analysis of C-276's metallurgical design and corrosion-resistant system, see our detailed guide to Hastelloy C-276 alloy .

Hastelloy C-22

  • Higher chromium content
  • Excellent resistance to oxidizing media
  • Strong pitting and crevice corrosion resistance
  • Excellent performance in mixed chemical environments
  • Strong resistance to wet chlorine and contaminated media
  • Well suited to welded process equipment

Hastelloy C-276

  • Approximately 16% chromium
  • Very strong reducing-acid resistance
  • Excellent broad-spectrum corrosion resistance
  • Strong resistance to pitting and crevice corrosion
  • Well established in chemical processing
  • Can be advantageous in strongly reducing environments
Key difference: C-22 increases chromium relative to C-276, shifting the alloy's corrosion-resistance balance toward stronger performance in oxidizing and mixed environments while maintaining substantial resistance to reducing conditions.

4. Hastelloy C-22 Corrosion Resistance

Corrosion resistance is the primary reason engineers specify Hastelloy C-22. Its high chromium, molybdenum and tungsten content gives the alloy a broad corrosion-resistance envelope.

~22% Chromium
~13% Molybdenum
~3% Tungsten
Ni Balance Matrix

Resistance to Oxidizing Media

The relatively high chromium content provides an important advantage in oxidizing environments. C-22 is commonly considered for chemical systems containing oxidizing contaminants that can be challenging for lower-chromium nickel alloys.

Pitting and Crevice Corrosion

The combined influence of chromium, molybdenum and tungsten makes C-22 highly resistant to localized corrosion. This is particularly important for heat exchangers, piping, vessels, pumps and other equipment containing stagnant or geometrically shielded areas.

Stress Corrosion Cracking

C-22 also offers strong resistance to chloride-induced localized corrosion and stress corrosion cracking compared with many conventional stainless steels and lower-alloyed materials.

5. Metallurgy and Microstructural Stability

Hastelloy C-22 is a solid-solution-strengthened nickel-based alloy. Its corrosion performance depends not only on nominal composition but also on maintaining a suitable metallurgical condition during manufacturing and service.

01

Ni Matrix

Provides the continuous face-centered-cubic matrix for the alloy.

02

Cr Addition

Enhances passivation and resistance to oxidizing environments.

03

Mo + W

Improve localized and reducing-environment corrosion resistance.

04

Low C + Si

Helps reduce undesirable precipitation during welding and fabrication.

The very low carbon and controlled silicon content are particularly important for welded structures because excessive precipitation in heat-affected zones can reduce corrosion resistance.

Processing consideration: Prolonged exposure within intermediate temperature ranges should be carefully controlled because unwanted intermetallic or topologically close-packed phases can adversely affect ductility and corrosion performance.

6. Mechanical and Physical Properties

Hastelloy C-22 combines corrosion resistance with useful mechanical strength and ductility. Actual values depend on product form, manufacturing route, heat treatment and applicable specification.

Property Typical / Reference Value
Density Approximately 8.69 g/cm³
Melting Range Approximately 1335–1399°C
Elastic Modulus Approximately 206 GPa
Tensile Strength at Room Temperature ≥ 690 MPa
Yield Strength ≥ 310 MPa
Elongation ≥ 45%

For procurement, design calculations and pressure-equipment applications, engineers should always verify the required mechanical properties against the applicable material specification and product form rather than relying on generic handbook values.

7. Hastelloy C-22 Heat Treatment

Solution annealing is used to restore a suitable metallurgical condition following hot working, forming or other manufacturing operations.

Typical Solution-Annealing Approach

01

Heat

Heat the material into the appropriate solution-annealing range.

02

Hold

Maintain sufficient temperature for metallurgical homogenization.

03

Rapid Cooling

Cool rapidly to limit undesirable precipitation.

04

Inspect

Verify dimensions, surface condition and required mechanical properties.

Commonly referenced solution-treatment ranges are approximately 1065–1135°C, depending on the applicable specification and product form. Exact treatment parameters should be controlled according to the relevant material standard and supplier procedure.

Important: Avoid uncontrolled prolonged exposure in temperature ranges where detrimental intermetallic phases may form. Cooling practice is therefore an important part of the heat-treatment procedure.

8. Welding and Fabrication

Hastelloy C-22 is designed to provide good weldability while maintaining corrosion resistance in welded components. This makes it particularly attractive for fabricated chemical-processing equipment.

Key Welding Considerations

  • Use controlled heat input and appropriate interpass temperatures.
  • Maintain clean surfaces before welding.
  • Minimize contamination from carbon steel and other materials.
  • Use filler metals appropriate for the C-22 chemistry.
  • Control the heat-affected zone to minimize undesirable precipitation.
  • Verify the final welded condition against the project specification.

ERNiCrMo-10 is commonly associated with C-22 welding applications. Filler selection should be based on the base material, joint design, service environment and applicable welding specification.

Why filler selection matters: The weld metal should not introduce a significantly weaker corrosion resistance profile than the parent alloy, particularly when equipment will operate in mixed oxidizing and reducing environments.

9. Hastelloy C-22 Applications

The broad corrosion-resistance envelope of C-22 makes it suitable for applications where process chemistry is complex, variable or contaminated.

Chemical Processing

Reactors, heat exchangers, columns, pumps, valves and piping exposed to aggressive mixed chemical environments.

Pollution Control

FGD equipment, absorber components, spray systems, mist eliminators and wet scrubber systems.

Pharmaceutical

High-purity process equipment, reactors, crystallizers and piping requiring corrosion resistance and cleanability.

Marine & Desalination

Pumps, seawater systems and components exposed to chloride-rich marine environments.

Nuclear Processing

Selected equipment used in nuclear fuel processing and aggressive waste-management environments.

Pulp & Paper

Components exposed to chlorine-containing bleaching and process chemicals.

10. Hastelloy C-22 vs C-276: Which Alloy Should You Select?

There is no universal winner between C-22 and C-276. The correct alloy depends on the actual process chemistry, temperature, contaminants, corrosion mechanism, fabrication method and required service life.

Choose C-22 when

Mixed or Oxidizing Conditions

The process contains oxidizing species, chlorides or changing chemical conditions and a broad corrosion-resistance margin is required.

Consider C-276 when

Strongly Reducing Conditions

The process is dominated by strongly reducing acids where the C-276 chemistry may provide an appropriate performance balance.

Always evaluate

Actual Process Chemistry

Consider acid concentration, temperature, chlorides, oxidizers, flow conditions, crevices, welds and expected contamination.

Engineers should therefore select C-22 or C-276 based on actual corrosion data and service conditions rather than simply choosing the alloy with the higher nominal alloying content.

11. Hastelloy C-22 Product Forms

Hastelloy C-22 can be supplied in different product forms depending on equipment design, machining requirements and fabrication route. Alloy-Ronsco's nickel-alloy product range covers several forms suitable for industrial applications.

Explore Hastelloy C-22 Product Forms

Select the product form that best matches your engineering, fabrication and procurement requirements.

For example, the nickel alloy bar and rod range includes Hastelloy C22 and C276 bar products, while the nickel alloy forgings range includes Hastelloy C22 and C276 forged products.

When selecting a product form, buyers should specify alloy grade, applicable standard, dimensions, quantity, heat-treatment condition, inspection requirements and required documentation.

12. Hastelloy C-22 FAQ

What is Hastelloy C-22?

Hastelloy C-22 is a nickel-chromium-molybdenum-tungsten corrosion-resistant alloy identified as UNS N06022. It is designed for demanding chemical environments, particularly mixed oxidizing and reducing conditions.

What is the composition of Hastelloy C-22?

C-22 is primarily nickel, with approximately 20–22.5% chromium, 12.5–14.5% molybdenum and 2.5–3.5% tungsten, together with controlled levels of iron, carbon, silicon and other minor elements.

Is Hastelloy C-22 better than C-276?

Neither alloy is universally better. C-22's higher chromium content provides an advantage in many oxidizing and mixed environments, while C-276 remains highly competitive in strongly reducing chemical environments.

Is Hastelloy C-22 resistant to pitting and crevice corrosion?

Yes. The combination of chromium, molybdenum and tungsten provides strong resistance to localized corrosion, making C-22 suitable for chloride-containing and contaminated process environments.

Can Hastelloy C-22 be welded?

Yes. C-22 has good weldability when appropriate procedures, filler metals, heat input and contamination controls are used.

What products are available in Hastelloy C-22?

Depending on specification and supplier capability, C-22 can be supplied in forms such as bar, rod, plate, sheet, coil and forgings. Alloy-Ronsco provides multiple C-22 product forms for industrial applications.

13. Conclusion

Hastelloy C-22 is best understood as a carefully balanced nickel-based corrosion-resistant alloy rather than simply a stronger alternative to every other Hastelloy grade.

Its relatively high chromium content improves resistance to oxidizing environments, while molybdenum and tungsten maintain strong resistance to reducing acids and localized corrosion. Low carbon and controlled silicon further support metallurgical stability during fabrication.

Compared with C-276, C-22 is particularly attractive when process conditions can shift between oxidizing and reducing states or when chloride contamination and localized corrosion are major concerns.

Final selection principle: Choose Hastelloy C-22 based on the actual chemical environment, temperature, corrosion mechanism, fabrication condition and required service life. For strongly reducing environments, C-276 may remain the more appropriate engineering choice.

Need Hastelloy C-22 for Your Application?

Alloy-Ronsco supplies nickel-based alloys and corrosion-resistant materials in multiple product forms, including Hastelloy C-22. Contact our team with your required grade, dimensions, quantity and application requirements.

Technical note: Material properties and processing parameters may vary according to product form, applicable specification, heat-treatment condition and manufacturing route. Engineering design and procurement decisions should be based on the applicable material standard and project requirements.
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